Product ID:CRAMOLIN R-5 SPRAY
MSDS Date:08/05/1986
FSC:6850
NIIN:00N012136
MSDS Number: BQNYZ

CAIG LABORATORIES,INC

1175 INDUSTRIAL AVENUE
ESCONDIDO, CA 92025
US

Emergency Phone: 800-441-3637;619-743-7143

Info Phone: 619-743-7143

Cage: 55403

CAIG LABORATORIES INC

POWAY, CA 92064 US

Telephone: 858-486-8388

Cage: 55403

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 60.0%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

DICHLORODIFLUOROMETHANE (FREON 12)

CAS: 75-71-8

RTECS: PA8200000

Fraction By Weight: 35%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CRAMOLIN RED OIL R-100L

Fraction By Weight: 5%

OSHA PEL N/K

ACGIH TLV: N/K

LIFE-SUSTAINING USES IN HUMANS EXPOSED TO

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

INHALATION/SKIN/INGESTION .

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:LC50 RAT INHALATION 300,000 PPM/2 HR
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:VAPOR IS HEAVIER THAN AIR AND CAN
CAUSE SUFFOCATION BY REDUCING OXYGEN AVAILABLE FOR
BREATHING.INHALATION OF HIGH VAPOR CONCENTRATIONS MAY CAUSE
DEATH.CAN BE ASPIRATED INTO THE LUNGS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES/SKIN:N/K .INGESTION:NOT LIKELY TO BE
HAZARDOUS BY INGESTION.INHALATION:BREATHING HIGH VAPOR
CONCENTRATIONS MAY CAUSE LIGHTHEADEDNESS,GIDDINESS,SHORTNESS OF
BREATH,& MAY LEAD TO NARCOSI S,CARDIAC
IRREGULARITIES,UNCONSCIOUSNESS.
Medical Cond Aggravated by Exposure:CARDIOVASCULAR DISEASE

First Aid:EYES:IMMED FLUSH W/ PLENTY OF WATER FOR AT LEAST 15 MIN.CALL
MD.SKIN:FLUSH W/ H2O.GET MED ATTN IF IRRIT PRESENT. INGEST:NO
SPECIFIC INTERVENTION INDICATED.NOT LIKELY TO BE HAZARDOUS BY
INGEST.DO NOT I NDUCE VOMIT.ASPIR HAZ IS GREATER THAN TOXICITY
HAZ.INHAL: REMOVE TO FRESH AIR.CALL MD.IF NOT BRTHG,GIVE ARTF
RESP,PREF MOUTH-TO- MOUTH.IF BRTHG DFCLT GIVE O2.MD
NOTE:TRICHLOROTRIFLUOROETHANE (SEE SU

Flash Point Method:PMCC
Flash Point:SEE SUPP DATA
Extinguishing Media:IF CRAMOLIN OIL RESIDUE IGNITES USE FOAM,CARBON
DIOXIDE,OR HALON.
Fire Fighting Procedures:WEAR PRESSURE DEMAND SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODS MAY INCL CHLORIDES,
FLUORIDES & PHOSGENE .OPEN FLAME/GLOWING METAL MAY PRDCE
HYDROCHLORIC & HYDROFLUORIC ACIDS,POSS CARBONYL HALIDES.

Spill Release Procedures:VENTILATE AREA UNTIL ODOR IS GONE.USE SELF-
CONTAINED BREATHING APPARATUS FOR NECESSARY PROLONGED
EXPOSURE.AFTER FREONS HAVE BEEN REMOVED BY VENTILATION,CLEAN UP
OILY RESIDUE WITH STANDARD SOAP OR DET ERGENT SOLUTION.
Neutralizing Agent:N/K

Handling and Storage Precautions:DO NOT EXPOSE ANY AEROSOL CAN TO
SUNLIGHT/ HIGH TEMPS (ABOVE 120F,48.89C) TO PREVENT POSS
BURSTING.ALL AEROSOL CAUTIONS APPLY.USE IN VENTILATED AREA.
Other Precautions:NO SMOKING IN AREA OF USE.DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING,OPEN FLAMES,OR HOT SURFACES.HEAT MAY CAUSE
THE FORMATION OF HCL AND/OR PHOSGENE .AS WITH ANY CHEMICAL,USE ONLY
AS DIRE CTED AND WASH HANDS AFTER USE.

Respiratory Protection:NOT NECESSARY UNLESS USED IN AN UNVENTILATED
AREA OR IN HIGH CONCENTRATIONS.
Ventilation:KEEP WINDOWS OPEN.USE LOCAL EXHST WHEN USED REPEATEDLY IN
QUANTITY.USE MECHANICAL EXHAUST TO PVNT BUILDUP IN LOW AREAS.
Protective Gloves:NOT NECESSARY
Eye Protection:SUGGESTED WHEN USING ANY AEROSOL.
Other Protective Equipment:NOT NECESSARY WITH ADEQUATE VENTILATION.
Work Hygienic Practices:AVOID BREATHING VAPORS AND CONTACT WITH SKIN OR
EYES.USE ADEQUATE VENTILATION.WASH HANDS AFTER USE.
Supplemental Safety and Health
FL PT:MIX IS NONFLAMMABLE.CRAMOLIN OIL RESIDUE FL PT 338F,170C.SOL IN
H2O:FREON TF & OIL MIX <0.2% BY WT.FIRST AIR PROC:&
DICHLORODIFLUOROMETHANE MATLS HAVE PRDCD SENSITIZATION OF THE
MYOCARDIUM TO EP INEPHRINE IN LAB ANIMALS & COULD HAVE ASIMILAR
EFFECT IN HUMANS.USE ADRENERGICS (EPINEPHRINE) ONLY FOR (SEE ING 4)

Boiling Pt:B.P. Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Vapor Density:N/K
Spec Gravity:1.57 G/CC
Evaporation Rate & Reference:0.1,CCL4=1
Solubility in Water:SEE SUPP DATA
Appearance and Odor:LIGHT PINK AS MIX.RED COLOR AFTER SOLVENT HAS
EVAPORATED.SLIGHT ETHEREAL ODOR.

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS-POWDERED ALUMINUM, ZINC,BERYLLIUM,ETC.
Stability Condition to Avoid:AVOID OPEN FLAMES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:CHLORIDES, FLUORIDES AND PHOSGENE . AT
HIGH TEMPS CAN FORM HYDROCHLORIC & HYDROFLUORIC ACIDS, CARBONYL
HALIDES.
Conditions to Avoid Polymerization:OPEN FLAMES AND HIGH TEMPERATURES.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .EPA HAZARDOUS WASTE NUMBERS
F001 AND F002 MAY APPLY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.